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41.
Observation of surface-plasmon phenomena that are dependent upon the handedness of the circularly polarized incident light (spin) is presented. The polarization-dependent near-field intensity distribution obtained in our experiment is attributed to the presence of a geometric phase arising from the interaction of light with an anisotropic and inhomogeneous nanoscale structure. A near-field vortex surface mode with a spin-dependent topological charge was obtained in a plasmonic microcavity. The remarkable phenomenon of polarization-sensitive focusing in a plasmonic structure was also demonstrated. 相似文献
42.
We present a mild and efficient method for the completely regioselective alcoholysis of styrene oxides utilizing a cooperative Br?nsted acid-type organocatalytic system comprised of mandelic acid (1 mol %) and N,N'-bis-[3,5-bis-(trifluoromethyl)phenyl]-thiourea (1 mol %). Various styrene oxides are readily transformed into their corresponding beta-alkoxy alcohols in good to excellent yields at full conversion. Simple aliphatic and sterically demanding, as well as unsaturated and acid-sensitive alcohols can be employed. 相似文献
43.
Kleiner RE Brudno Y Birnbaum ME Liu DR 《Journal of the American Chemical Society》2008,130(14):4646-4659
The DNA-templated polymerization of synthetic building blocks provides a potential route to the laboratory evolution of sequence-defined polymers with structures and properties not necessarily limited to those of natural biopolymers. We previously reported the efficient and sequence-specific DNA-templated polymerization of peptide nucleic acid (PNA) aldehydes. Here, we report the enzyme-free, DNA-templated polymerization of side-chain-functionalized PNA tetramer and pentamer aldehydes. We observed that polymerization of tetramer and pentamer PNA building blocks with a single lysine-based side chain at various positions in the building block could proceed efficiently and sequence specifically. In addition, DNA-templated polymerization also proceeded efficiently and in a sequence-specific manner with pentamer PNA aldehydes containing two or three lysine side chains in a single building block to generate more densely functionalized polymers. To further our understanding of side-chain compatibility and expand the capabilities of this system, we also examined the polymerization efficiencies of 20 pentamer building blocks each containing one of five different side-chain groups and four different side-chain regio- and stereochemistries. Polymerization reactions were efficient for all five different side-chain groups and for three of the four combinations of side-chain regio- and stereochemistries. Differences in the efficiency and initial rate of polymerization correlate with the apparent melting temperature of each building block, which is dependent on side-chain regio- and stereochemistry but relatively insensitive to side-chain structure among the substrates tested. Our findings represent a significant step toward the evolution of sequence-defined synthetic polymers and also demonstrate that enzyme-free nucleic acid-templated polymerization can occur efficiently using substrates with a wide range of side-chain structures, functionalization positions within each building block, and functionalization densities. 相似文献
44.
We prove the differentiability of Lipschitz maps X → V, where X denotes a PI space, i.e. a complete metric measure space satisfying a doubling condition and a Poincaré inequality, and V denotes a Banach space with the Radon–Nikodym Property (RNP). As a consequence, we obtain a bi-Lipschitz nonembedding theorem
for RNP targets. The differentiation theorem depends on a new specification of the differentiable structure for PI spaces
involving directional derivatives in the direction of velocity vectors to rectifiable curves. We give two different proofs
of this, the second of which relies on a new characterization of the minimal upper gradient. There are strong implications
for the infinitesimal structure of PI spaces which will be discussed elsewhere. 相似文献
45.
Jaan Unger Marcus Stiemer Alexander Brosius Bob Svendsen Heribert Blum Matthias Kleiner 《International Journal of Solids and Structures》2008,45(2):442-459
The purpose of this work is the development and application of strategies to identify material model parameters for metals at high strain-rates using data obtained from high-speed electromagnetic metal forming. To this end, a staggered algorithm for the finite-element-based numerical solution of the coupled electromagnetic-mechanical boundary-value problem has been developed based on mixed Eulerian–Lagrangian multigrid methods. On this basis, the parameter determination together with a sensitivity analysis and error estimation are carried out. After verifying the validity of this approach using synthetic data sets, it is applied to the identification of material parameters using experimental results from electromagnetic tube forming. 相似文献
46.
Israel Kleiner 《Elemente der Mathematik》1998,53(1):18-35
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49.
H. Tauber I. S. Kleiner R. Fischer und W. Paulus 《Fresenius' Journal of Analytical Chemistry》1937,108(1-2):69-70
Ohne Zusammenfassung 相似文献
50.